Dibromoindium(III) cations as a π-Lewis acid: characterization of [IPr·InBr2][SbF6] and its catalytic activity towards alkynes and alkenes.

نویسندگان

  • Bastien Michelet
  • Jean-Rémy Colard-Itté
  • Guillaume Thiery
  • Régis Guillot
  • Christophe Bour
  • Vincent Gandon
چکیده

[IPr·InBr2][SbF6] (2) (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) has been synthesized and characterized in the solid state. This complex proved to be a very active catalyst for hydroarylations, transfer hydrogenations, and cycloisomerizations.

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عنوان ژورنال:
  • Chemical communications

دوره 51 34  شماره 

صفحات  -

تاریخ انتشار 2015